lower heating value (LLV) (LLV)

The heat produced by combusting one unit of a substance, at atmospheric pressure under conditions such that all water in the products remains in the form of vapor. The net heat of combustion is calculated from the gross heat of combustion at 20°C by subtracting 572 cal/g (1030 Btu/lb) of water derived from one unit mass of sample, including both the water originally present as moisture and that formed by combustion. This subtracted amount is not equal to the latent heat of vaporization of water because the calculation also reduces the data from the gross value at constant volume to the net value at constant pressure. The appropriate factor for this reduction is 572 cal/g. (Source: Domalski, E.S.; Milne T.A., ed. Thermodynamic Data for Biomass Materials and Waste Components. The ASME Research Committee on Industrial and Municipal Wastes, New York: The American Society of Mechanical Engineers, 1987)